VATIS Update Waste Management . Jan-Feb 2008
IN THE NEWS
United Nations examines mercury pollution
Governments must speed up efforts to deliver an international agreement on mercury, said Mr. Achim Steiner, executive director of the UN Environment Programme (UNEP) at a major summit examining ways to reduce environmental sources of the poisonous metal. He said scientists have been warning about the dangers to human health, wildlife and the wider environment for well over a century but a global response has yet to be mounted. He pointed out that a comprehensive and decisive response to the global challenge of mercury was not in place and that needed to be urgently addressed.
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Indian guidelines for e-waste management
The Central Pollution Control Board (CPCB) of India has published the ‘Draft Guidelines for Environmentally Sound Management of E-Waste’ for the State Pollution Control Boards and Pollution Control Committees of the Union Territories and the industries handling electrical and electronic waste (e-waste). A Task Force has been set up by the Ministry of Environment and Forests (MoEF) for their finalization.
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China’s wastewater treatment industry set to take off
The water and wastewater treatment industry of China is expected to expand rapidly, with international and domestic venture capitalists showing great interest in the business opportunities offered by the deteriorating water quality and the severe water shortages, especially in northern China. Mr. Liu Junjie, general manager of the Duoyuan Global Water Operation Co. Ltd. says that about 80 per cent of the surface water and 40 per cent of underground water in China is contaminated.
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Sri Lanka gets Swedish aid to clean up industrial pollution
The Swedish government has given Sri Lanka a soft loan to set up wastewater treatment plants in two of the suburbs of Colombo city known for clusters of factories that discharge untreated waste into waterways, said a statement from Sri Lanka’s Finance Ministry. The US$91.9 million dollars for the project, implemented through the National Water Supply and Drainage Board, is free of interest. The amount will be used to manage pollution by collecting industrial and domestic wastewater, treating in central plants, and disposal in environmentally safe ways. About 204 industries and 35,000 residents in Ratmalana and Moratuwa, south of Colombo, and about 130 industries and 28,500 residents of the northern Ja-ela and Ekala suburbs would come under the project. Source: www.lankabusinessonline.com |
Pakistan to take legal action against polluting hospitals
The Environmental Protection Department (EPD) of Pakistan is taking legal action against Lahore’s public and private sector hospitals, which have failed to implement “in letter and spirit” the Hospital Waste Management Rules (HWMR) 2005. As a first step, EPD will start issuing Environmental Protection Orders (EPO) to the respective hospital administrations. The decision was prompted by EPD’s concern over the failure of the Environmental Wing of City District Government of Lahore in enforcing HWMR.
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Japan to assist others with e-waste recycling
The Environment Ministry of Japan plans to help five South East Asian countries – Viet Nam, Thailand, the Philippines, Malaysia and Cambodia – to recycle used home electronics appliances. The Japanese government will also seek ways to help the countries neutralize toxic materials such as polychlorinated biphenyls, including those generated by hospitals. The initiative is in line with the Japanese cabinet policy adopted last June to encourage international co-operation in the field of recycling.
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Malaysia drafts new solid waste rules
The Housing and Local Government Ministry of Malaysia is drafting new regulations related to solid wastes after Parliament passed the Solid Waste and Public Cleansing Management Act last July. The Minister Datuk Seri Ong Ka Ting said the new rules will be fine-tuned by the Attorney-General’s office before its implementation from April 2008.
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India’s e-waste generation on a new high
India generated 330,000 tonnes of e-waste in 2007 as dumping from developed countries and informal recycling added to environmental degradation, says a recent study. E-waste in the country is expected to touch 470,000 tonnes by 2011, revealed the study commissioned by the Manufacture’s Association for Information Technology (MAIT), the apex body representing India’s IT sector, and GTZ, Germany’s Technical Cooperation Agency. Said to be a first to inventorize e-waste in the country, the study focused only on the waste stream of television sets, computers and mobile handsets. It revealed that of the total 330,000 t of e-waste generated annually, only 19,000 t are recycled owing to the high refurbishing and reuse and the poor recycling infrastructure.
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PLASTIC WASTES
Shredding plastic film
Vecoplan LLC in the United States has launched an industrial shredder for the rapid shredding of plastic film. The RG42K-XL F features SureCut shredding system that delivers built-in, two-stage auxiliary size reduction in a single pass. Among other features are a specially reinforced, close-tolerance screen configuration, and an application-specific ‘wedge’ fixed counter knife. Designed for high throughput, the shredder also has built-in metering capabilities and thermal monitoring controls.
Source: www.recyclinginternational.com |
Agglomerating thermoplastic waste
PFV Plast-Agglomerator, from the German size reduction machinery manufacturer Pallmann, is built for recycling thermoplastic waste and compounds for reintroduction to the production stream. The throughput capacities range from around 60 kg to more than 300 kg per hour.
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Reclaiming plastics from junkyard cars
Once plastics have been built into a car, they are rarely recycled. The shredded plastic parts, compressed into granulate material, are usually too indiscriminately mixed to permit any further use. In a joint project with Toyota and Sicon, researchers at the Fraunhofer Institute for Process Engineering and Packaging IVV in Germany have now found a way of separating the different plastics. The researchers laid the foundation with CreaSolv® and developed a special solvent that removes polyolefins from the granulate. The polymer dissolves in the solvent, while the other plastics remain in the granulate. The solvent is separated from the polyolefin and re-used.
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Dry-cleaning waste plastic to reduce water consumption
A novel ‘dry cleaning’ technology for plastic waste could lead to significantly less water consumption. Developed by Germany’s Pla.to GmbH, the machines remove paper labels and adhering dirt from the plastics. The dry mechanical cleaning system for dirty plastic flakes and films can reduce water consumption by up to 90 per cent, and cut waste levels by half, compared with wet washing plants.
Source: www.morethanwaste.com |
Optical colour sorters for plastics recycling
Colour plastics sorters from Buhler Sortex, the United Kingdom, are an obvious choice for the plastics recycling industry and are rapidly becoming an industry standard. Its Sortex Z+ range of optical colour sorters are specially equipped for the PVC recycling industry. These machines can sort by colour and shape a wide variety of plastics, including PVC, PET, HDPE, LDPE, PVB and PP. They have the ability to remove foreign materials such as rubber, metal, paper, glass, wood and many other contaminants.
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Scrap tyres as a roofing medium
A co-operative venture in the United Kingdom, involving the Airport Business Centre (ABC), Crumb Rubber Ltd. and London’s Queen Mary University, has developed a new roof tile employing recycled rubber from used tyres. Successful trials conducted by the three organizations have proved that ultra-fine vulcanized crumb rubber derived from post-consumer truck tyres can be used to make a composite roofing slate.
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New granulator for PVC window profiles
Hosokawa Alpine, which forms part of Japan’s Hosokawa Group, has introduced the 45/71 PM Profile Granulator to assist PVC window profile manufacturers’ in-house recycling activities. The granulator is at the heart of a complete system designed to comminute mitre sections, small parts as well as reject profiles up to a length of 7 m.
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ELECTRONIC WASTES
E-waste separation with e-Sort
The e-Sort, designed specifically for automated sorting of electrical and electronic waste materials (WEEE), is a high-speed, optical system that separates individual plastic resins, printed circuit boards and metals from shredded material, says its manufacturer MSS Inc., the United States. The machine combines the latest near infrared and metal identification technology (colour optical) in a computerized system for accurate sorting of WEEE materials.
Source: www.recyclinginternational.com |
CRT recycling plant
CRT Recycling Limited, the United Kingdom, has opened a new £1.5 million recycling plant for cathode ray tubes (CRTs) in Flintshire, North Wales. The plant uses state-of-the-art technology developed jointly with RTG of Germany to process 25,000 tonnes of CRTs each year, including CRTs received in a broken state. The process allows funnel glass and panel glass to be separated mechanically, allowing processed glass to be used in markets other than CRT manufacturing.
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E-waste processing and materials recovery
Electrovac–Fabrikation Elektrotechnischer Spezialartikel Gesellschaft, Austria, has been assigned a United States patent on a method of processing electronic and electrical scrap to recover materials such as base metals, precious metals and ceramics. The invention aims at optimized recovery of non-ferrous materials from different e-scrap, by providing the capability of changing the process parameters for optimum recovery of selected materials.
Source: www.freepatentsonline.com |
BIOMEDICAL/HEALTHCARE WASTES
Multi-process phytoremediation system for POPs
In the last few years, the University of Waterloo in Canada has been studying multi-process phytoremediation system (MPPS) for removing persistent organic pollutants (POPs) and metals from contaminated soils. University researchers have recently demonstrated POP degradation through MPPS based on accelerated remediation kinetics from multiple physical and biological processes. Greenhouse and pilot tests have indicated that the process removes polycyclic aromatic hydrocarbons, total petroleum hydrocarbons (TPHs) and chlorinated hydrocarbons (CHCs) from soils while stabilizing metals.
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Preparation of a catalyst for dioxin removal
SK Corporation from the Republic of Korea has secured a European patent on a process for the preparation of a catalyst for removing dioxin. The catalyst is prepared by recycling a spent catalyst discharged from a hydro-desulphurization process of an oil refinery in which the spent catalyst comprises an alumina support (preferably, g-alumina) with a large specific surface area and impregnated with vanadium. The spent catalyst is mixed with titania impregnated with tungsten to prepare a catalyst comprising suitable metal components. The catalyst has excellent dioxin removal performance and low cost because of recycling the spent catalyst.
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Sequential thermal desorption and decomposition
An onsite process that combines indirect thermal desorption (ITD) with base-catalysed decomposition (BCD) is operating in semi-process mode at the former Spolana chemical manufacturing complex in Neratovice, Czech Republic. Over the course of operation, the plant will treat POPs in 35,000 t of soil and contaminated building rubble, 1,000 t of contaminated concentrate generated by first ITD stage, and 200 t of pesticide waste intermediate compounds. Site characterization had identified high levels of POPs in soil, with about 1,300 mg/kg hexachlorobenzene, 45,000 ng/kg dioxin toxic equivalency (TEQ) and 200 mg/kg lindane.
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Process for treating contaminated solid-liquid mixture
The Commonwealth Scientific and Industrial Research Organization of Australia has patented a process for treating a contaminated solid and liquid mixture. The method can be applied to the decontamination of liquids such as water and solids such as soils or other substrates containing contaminants such as polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and certain pesticides. It has two main steps: subjecting the mixture to cavitation wherein a portion of the contaminant gets chemically decomposed; and then introducing a pre-determined biological species into the treated mixture to complete the decontamination.
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Combo mechanical and chemical soil treatment
In New Zealand, the Ministry for the Environment and Tasman District Council are collaborating in clean-up and reuse planning for the Fruitgrowers Chemical Company (FCC) site, the country’s most highly contaminated area. In 2004, an onsite demonstration was held to evaluate an innovative technology that uses mechanical energy to promote reductive dehalogenation of POPs in soil and sediment. Successful results of the demonstration of Mechanochemical DestructionTM (MCD) led to full-scale application of the technology later that year to treat surface and sub-surface material containing high concentrations of DDX (DDT, DDD and DDE) and ADL (aldrin, dieldrin and lindane).
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Bimetallic treatment for PCBs removal
To address limitations of traditional abatement methods for polychlorinated biphenyls (PCBs) in paints, researchers at the Kennedy Space Centre of the United States National Aeronautics & Space Administration (NASA) and the University of Central Florida have developed and patented the “bimetallic treatment system” (BTS) for paints. This innovative technology consists of a solvent solution (such as ethanol or d-limonene) that contains a catalysed zero-valent metal (such as magnesium coated with palladium). BTS is first applied to the painted surface. The solution then extracts the PCBs from the paint, while the micro-scale metal catalysts in the solution degrade them into benign by-products.
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INDUSTRIAL WASTEWATER
Biological treatment of wastewater
WaterStax biological treatment systems, from Water Maze in the United States, employ the latest biotechnology for treating and recycling commercial and industrial wastewater. The natural, chemical-free bioremediation technology economically removes oils, hydrocarbons, grease, herbicides, pesticides and insecticides. A blend of microbes literally eats contaminants, converting them into water and carbon dioxide. However, as there are some human allergens that may not be treated by bioremediation alone, WaterStax also offers:
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Recovery of organic carbon from industrial wastewater
A joint research by scientists from Kasetsart University, Thailand, and University of Tokyo, Japan, applied a photosynthetic bacterial pond system for the treatment of wastewater from the food industry and recovery of carbon in the form of purple non-sulphur bacteria (PnSB). The effect of infra-red transmitting filter on the selection of microbial groups in the system was investigated.
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Wastewater system for FGD scrubber
Siemens Water Technologies (SWT) will provide a system to treat wastewater from a flue gas desulphurization (FGD) scrubber being built at Allegheny Energy’s Hatfield Ferry Power Station in Pennsylvania, the United States. The system will de-saturate the wastewater as well as remove suspended solids and heavy metals from the scrubber’s waste stream to allow the safe discharge of the water.
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Bio-augmentation technology for wastewater treatment
A researcher from Jai Hind College, Mumbai, India, has studied the use of bio-augmentation for enhancing the biodegradation of organic matter in wastewater. Mr. M.T. Pandya has concluded that the biodegradability of organics can be enhanced using bio-augmentation and advanced oxidation processes (AOP) for aerobic/anaerobic treatment programmes.
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New non-chemical process to clean up produced water
ONGC, India’s state-owned oil company, recently patented a process to remove oily effluent from produced water. The chemical-free electro-flotation method assures additional oil recovery from a process stream with low manpower demand. While conventional flotation methods use a separate gas source to pump gas bubbles into the liquid, the electro-flotation process generates the gas on site.
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Electro-catalytic oxidation of oily wastewater
Electro-catalytic oxidation (ECO) relies on injection of suitable biological and chemical catalysts to aid further separation and coagulation of the wastewater components. The catalysed process stream is pumped through a Venturi-eductor aeration unit. Then the pre-catalysed and pre-aerated flow is subjected to a controlled DC electrical field within an electrode contact chamber, similar to ordinary electrolysis, in either a batch or a process mode.
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BIOREMEDIATION
Indigenous plants for bioremediation of closed mines
Shinil Corporation, the Republic of Korea, has developed a technology for the phytoremediation of soils polluted by heavy metals which involves creating mugwort (Common Wormwood or Artemisia vulgaris) cover on the polluted soil. Sulphur, which synthesizes chelate in plants, is supplied through soil improvers (pig manure and sewage sludge) to reduce toxicity and increase resistance when plants absorb heavy metals. The technology was successfully tested in an abandoned zinc mine. Contact: National Environmental Technology Information Centre, No. 613-2, Bulgwang-dong, Eunpyeong-gu, Seoul, Republic of Korea 122-706. Tel: +82 (2) 3800 553; Fax: +82 (2) 3800 545 E-mail: apecvc@kiest.re.kr Source: www.apec-vc.or.kr |
Solar bioreactor for groundwater remediation
A pilot-scale recirculation bioreactor has been operating at the Altus Air Force Base (AFB) in Oklahoma, the United States, since late 2003 to address a hotspot of volatile organic compounds (VOCs) in groundwater residing in weathered shale and fractured clay. A solar-powered pump operating in the extraction / collection trench keeps the groundwater recirculating through the 283 m3 bioreactor and into the aquifer to generate high-carbon leachate and enhance VOC biodegradation. Since its start-up, the system has transferred about 1,300 m3/year of organic carbon-enriched leachate from the bioreactor into the aquifer. Groundwater recirculation through the bioreactor has achieved a 98 per cent reduction in trichloroethene (TCE) concentration within the bioreactor and a 90-97 per cent reduction in plume toxicity in hotspot wells between the bioreactor cell and the extraction trench. |
Solar pump for groundwater circulation
Prior to project start-up, TCE concentrations in the hotspot were 19 mg/litre, and the plume extended nearly 1,000 m down-gradient of the landfill. The bioreactor was constructed immediately up-gradient of hotspot wells in an excavation of 9 m 9 m extending 3.4 m below ground surface (bgs). The cell was filled with a 1:1 mixture of sand and organic mulch consisting of woody material and cotton-gin trash. At the top of the cell a ground-water distribution system was set up between two layers of geotextile fabric. The cell was capped with a soil and native grass cover. The bioreactor relies on groundwater recirculation from down-gradient of the hotspot, which is located in the shallow aquifer 3.0-5.5 m bgs. The sites remote location and average solar radiation of 4-5 kWh/m2/day dictated the use of solar power to cut down construction and energy costs. Groundwater recirculation is carried out by a single, photovoltaic-powered, 3 inch submersible pump that maintains an average groundwater flow rate of about 3,500 litres/day. Pollutant degradation is monitored through a network of 18 wells. Evaluation of the bioreactor performance indicates dissolved organic carbon concentrations increased from <6 mg/litre prior to start-up to 120 mg/litre in shallow wells and 30 mg/litre in deeper wells. Increased concentrations of cis-1,2-dichloroethene, vinyl chloride and ethene indicate reductive dechlorination of TCE occurs in the bioreactor. For a more complete reductive dechlorination of TCE, a semi-soluble carbon substrate and a bioaugmentation culture were added to the bioreactor. Source: www.clu-in.org |
New process for bioremediation of contaminated soil
Canon Kabushiki Kaisha of Japan has been assigned a United States patent on a new process for remedying a contaminated soil. The new process involves freezing the contaminated region, and then injecting a micro-organism and a liquid/gas agent that is required to augment the micro-organisms ability to decompose the pollutant more rapidly and efficiently. The frozen region is then allowed to gradually thaw. A possible explanation, yet to be proved, for the process is as follows. When the soil is frozen and then thawed as a pre-treatment, freeze expansion in the pore space will widen the fine pore space of the soil into which the liquid agent will diffuse. Agitation of the soil water retained between the soil particles by this freezing and thawing will accelerate the contact between the injected liquid agent and ground-water. The process, well known in civil engineering field, causes swelling on freezing and consolidation on thawing in the soil. While a problem to be overcome in civil engineering works, it is favourable for the uniform distribution of a micro-organism. By adopting this freezing step, the present invention can promote the remediation efficiency and shorten the soil remediation period. Source: www.freepatentsonline.com |
Enhanced bioremediation technology
Microbial Groundwater Circulation Wells (mGCW), a concept from IEG Technologie GmbH, Germany, accelerate the natural biodegradation of organic compounds under aerobic or anaerobic conditions. These systems are specifically designed and configured to provide accelerated aerobic, enhanced anaerobic or sequential anaerobic/aerobic reactions. The special design of the wells produces a groundwater convection cell in the aquifer around the remediation well. The groundwater that circulates constantly transports both contaminants and existing degrading bacteria to the well. Small biologically active carbon reactors can be used inside the well for continuous growth, acclimation and augmentation. These reactors are found to have much higher levels of biodegradation and higher specific growth rates than other attached growth systems. Contaminants are selectively retained in the reactor, facilitating the selection and enrichment of micro-organisms that are capable of degrading pollutants. If necessary, added nutrients can be supplied to the accumulated micro-organisms. Another advantage of the mGCW is the oxygen-enriched groundwater generated by the system, which enhances the population growth of the micro-organisms in the aquifer, thus accelerating the degradation process. System variations include discontinuous circulation flow, reversing the circulation direction and installing different bioreactor configurations. These variations enable the technology to be easily customized to different contamination sites. Contact: IEG Technologie GmbH, Hohlbachweg 2, Gruibingen73344, Germany. Tel: +49 (7335) 96976-0; Fax: +49 (7335) 96976-40 E-mail: eduard.alesi@ieg-technologie.com Source: www.ieg-technologie.com |
Bioremediation of hydrocarbon-contamination
Exxon Research and Engineering Company, New Jersey, has secured a United States patent on its invention that provides an enhanced biodegradation process by applying to petroleum-contaminated water or soil microbial nutrients in controlled release. The process is capable of releasing the microbial nutrients over a sustained period of time, for example 1-6 months, which at 25C is a substantially linear rate. The rate of release of microbial nutrients, which is typically less than 5 per cent per day, can be increased by raising the temperature. The nutrients may include one or more nitrogen sources, such as urea and ammonium nitrate, and optionally phosphorous sources such as phosphates. Typically the nitrogen and phosphorous sources will be combined to provide an N:P ratio, preferably, of 10:1. Optionally, the nutrient cocktail may also contain micronutrients such as magnesium, iron, manganese and calcium at very low levels. The nutrients are coated with a material like an elastomeric sulphonated polymer such as ethylene-propylene diene terpolymer or EDPM that controls the release of nutrients to the environment. Source: www.freepatentsonline.com |
Vegetable oil as a bioremediation amendment
At University of Waterloo, Canada, biologists have studied the feasibility of using peanut (groundnut) oil as a cost-effective, non-toxic and biodegradable extractant for the remediation of soil contaminated by polycyclic aromatic hydrocarbons (PAHs). The scientists found that extraction efficiency was higher than 90 per cent when peanut oil at concentrations of 2.5-20 per cent was used to remove anthracene from garden soil. Optimal pH values for these extractions were 6 and 7. When soil spiked with a combination of 10 PAHs at 100 g/g was extracted with peanut oil at different temperatures, total PAH extraction efficiency increased from 51.5 per cent at 20C to 81.4 per cent at 60 C. A double extraction of weathered soil from a creosote-contaminated site using 5 per cent peanut oil, followed by another extraction with 5 per cent oil was better than a single 10 per cent oil extraction. Based on the results of the study, a process was conceptualized for the treatment of PAH-contaminated soil. Source: www.sciencedirect.com |
AIR POLLUTION CONTROL
Carbonation ash reactivation process for pollutant removal
The Ohio State University Research Foundation has obtained a United States patent on an invention that relates to methods and apparatus useful in mitigating major air pollutants – sulphur oxides (SOx) and nitrogen oxides (NOx) – and trace toxins from coal-fired combustors. Using this method or apparatus, a coal-fired combustor may be retrofitted to accommodate combined SOx/NOx removal technology for solid waste reduction and environmentally responsible use of dry flue gas desulphurization (FGD) product.
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Emissions removal from large diesel engines
The new “Cloud Chamber System” (CCS) technology, from Tri-Mer Corporation, the United States, attains high emissions removal efficiencies operating at flow volumes typical for stationary diesel exhaust from large diesel engines. CCS is engineered to deliver effective air pollution control for any exhaust application that produces coarse, fine or super fine particles – like those contained in stationary diesel engine exhaust. Efficiency levels are typically 99 per cent or greater. CCS simultaneously removes condensables and soluble gases.
Source: www.ogpe.com |
Complete treatment of flue gas NOx
The Civil Engineering Department of the Indian Institute of Technology Madras has developed a novel and effective system for the complete treatment of nitrogen oxides (NOx) from flue gases. The system comprises the photocatalytic or ozone oxidation of NOx followed by scrubbing and biological denitrification. Maximum photocatalytic oxidation of NOx is achieved by using powdered titania at a catalytic loading rate of 10 g/h, relative humidity of 50 per cent and a space time of 10 s. The used catalyst was regenerated and reused, while 72 per cent of NOx was recovered as nitric acid/nitrous acid (HNO3/HNO2) in the regeneration process.
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CO2 capture technology for coal-fired power plants
In the United States, BP Alternative Energy and Powerspan Corp. are working together to develop and commercialize an ammonia-based carbon dioxide (CO2) capture technology, developed by Powerspan and called ECO2, for coal-fired power plants. The post-combustion CO2 capture process is suitable for retrofit to the existing coal-fired, electric generating fleet as well as for new coal-fired plants. The captured CO2 would be sent for long-term storage deep underground.
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Heavy-duty diesel emissions control
The multinational BASF has developed a selective catalytic reduction (SCR) technology, which enables heavy-duty diesel trucks to comply with the stringent Euro 4 and Euro 5 emission regulations. Euro 4 standards stipulate a 30 per cent reduction of emissions of nitrogen oxides (NOx) from heavy-duty diesel vehicles, while an additional 40 per cent reduction in NOx emissions would be needed under Euro 5 standards.
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Removal of sulphur dioxide
Canada’s Cansolv Technologies Inc. (CTI), markets the Cansolv® System sulphur dioxide (SO2) scrubbing technology. The technology can be applied to flue gas desulphurization (FGD), sulphur recovery unit (SRU) and most other gaseous process streams in the power generation, refining, natural gas, sulphuric acid, smelter, and pulp & paper industries.
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